The thing to think about is that the angle of the ecliptic with the equator is not perpindicular, or, more to the point, it isn't perpindicular to our latitude.
Think of a line drawn from the sun when it rises, when it culminates and when it sets. This line drawn through the sky is the diurnal arc which will be parallel to the equator. The ecliptic, however, does not run along this same diurnal arc you just drew in the sky. Instead, the ecliptic is going to be at an angle to this arc, the diurnal arc is parallel to the equator and we know the eclipitc is angled to the equator hence its angled to the diurnal arc too. I realise we all know this on paper but it's important to keep it in mind.
Here's an image which shows the position of the sun at varying points of the day. Running through each sun is a faint line which depicts where the ecliptic was at at that time of the day. As I say, we probably all know this, but it helps to see it.
So when the earth rotates it's not rotating along the same line as the ecliptic.
Here's a short animation I just made to depict Aries and Libra as they rise. The thick red line can be imagined as an arc of 30 degrees of longitude which represents the tropical sign as it rises. Each frame of the animation elapses 15 minutes of clock time. Keep in mind that the earth rotates at a constant speed.
(I didn't embed these as the animation may get annoying)
Aries:
http://i.imgur.com/2soSh04.gif
Libra:
http://i.imgur.com/7crxzAz.gif
Notice that the rotation of the earth, as said above, is not along the same lines as the ecliptic, the rotation is not parallel to the ecliptic.
So here's what it looks like when I add in part of the diurnal arc in blue. It is along the blue line that we can imagine the earth to be spinning. So the longer the blue line the longer it will take the earth to allow a full sign to cross the horizon and rise.
Aries:
Libra:
Hopefully what should be obvious is that it's not so much the tilt of the ecliptic at the time that the sign is rising, it is the diurnal arc along which the ecliptic will rise at that time.
Clearly we see that Aries is much more slanted than Libra. And as a result, it is much shorter than Libra - the longer the line the longer it takes to rise as the earth rotates at a constant speed. Hence it takes Aries much quicker to rise than Libra, and also why we call Aries a crooked sign and Libra a straight one.
All these images were taken using Stellarium software, with me adding in the blue and red lines myself, and they were all taken at the latitude of London England. The further extreme the latitude, the more extreme will be the result.
Hope this helps.